1) Unbreakable: Bruce Willis/Robin Wright Penn
2) Eternal Sunshine of the Spotless Mind: Jim Carrey/Kate Winslet
3) Troy: Paris (Orlando Bloom) and Helen (Diane Kruger); Briseis (Rose Byrne) and Achilles (Brad Pitt)
4) The Hours: Meryl Streep/Ed Harris
5) Pearl Harbor: Rafe (Ben Affleck), Evelyn (Kate Beckinsale) and Danny (Josh Hartnett)
6) Sweet Home Alabama: Melanie (Reese Witherspoon) and Jake (Josh Lucas)
7) Tom (Hugh Jackman) and Izzi (Rachel Weisz)
8) Charmed: Phoebe (Alyssa Milano) and Cole (Julian Mcmahon)
9) Spiderman 2: Peter (Tobey Maguire) and Mary Jane (Kirsten Dunst)
10) Smallville: Chloe Sullivan (Allison Mack) and Clark Kent (Tom Welling); Chlark; Vessel Kiss
11) States of Grace: Lucas Fleischer/Rachel Emmers
12) The Family Man: Nicolas Cage/Tea Leoni
13) Memoirs of a Geisha: Ziyi Zhang/Ken Watanabe
14) Becoming Jane: Jane Austen (Anne Hathaway) and Tom Lefroy (James Mcavoy)
15) North and South: Margaret (Daniela Denby-Ashe) and John Thornton (Richard Armitage)
16) Jane Eyre (Ruth Wilson) and Edward Rochester (Toby Stephens)
17) King Arthur: Lancelot (Ioan Gruffudd) and Guinevere (Keira Knightley)
18) Pride and Prejudice: Mr. Darcy (Matthew Macfadyen) and Elizabeth Bennett
19) Rogue/Marie (Anna Paquin) and Logan/Wolverine
20) Deep Impact: Ron Eldard, Leelee Sobieski, Elijah Wood
21) Ben (Scott Speedman) and Felicity (Keri Russell)
22) Stardust: Charlie Cox/Claire Danes
23) Mary Bryant (Romola Garai) and Will (Alex O'Loughlin)
24) Max (Jessica Alba) and Logan (Michael Weatherly)
25) Moonlight: Mick St. John (Alex O'Loughlin) and Beth Turner (Sophia Myles); Mickbeth; first kiss
26) Kate (Meg Ryan) and Leopold
27) Hotel Rwanda: Don Cheadle/Sophie Okonedo
28) Blood and Chocolate: Vivian (Agnes Bruckner) and Aiden (Hugh Dancy)
29) Road to Avonlea: Gus Pike (Michael Mahonen) and Felicity King (Gema Zamprogna)
30) A Walk to Remember: Landon (Shane West) and Jamie (Mandy Moore)
31) Charly: Charly (Heather Beers) and Sam (Jeremy Elliott)
32) Lord of the Rings: Aragorn (Viggo Mortensen) and Eowyn (Miranda Otto)
33) Anne of Green Gables/Anne of Avonlea: Anne Shirley (Megan Follows) and Gilbert Blythe (Jonathan Crombie)
34) Superman Returns: Lois Lane (Kate Bosworth) and Clark (Brandon Routh)
35) Pirates of the Caribbean/POTC: Jack Sparrow (Johnny Depp) and Elizabeth Swann; Sparrabeth
36) Déjà vu: Denzel Washington/Paula Patton
37) Without a Trace: Sam Spade (Poppy Montgomery) and Martin (Eric Close)
38) Splendor in the Grass: Bud (Warren Beatty) and Deanie (Natalie Wood)
39) Veronica Mars (Kristen Bell) and Logan Echolls (Jason Dohring)
40) Jericho: Heather (Sprague Grayden) and Jake (Skeet Ulrich)
41) Jack (Leonardo Dicaprio) and Rose

http://www.youtube.com/watch?v=1Xliy2X6yxw